Hydroamination is the addition of an N-H bond of an amine across a carbon-carbon multiple bond of an alkene, alkyne, diene, or allene. In the ideal case, hydroamination is atom economical and green . [2]

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Example procedures for reductive amination using sodium triacetoxyborohydride [NaBH(OAc)3].

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A list of common conditions for reductive amination.

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The Buchwald–Hartwig amination is a chemical reaction used in organic chemistry for the synthesis of carbon–nitrogen bonds via the Palladium-catalyzed coupling reactions of amines with aryl halides.Although Pd-catalyzed C-N couplings were reported as early as 1983, Stephen L. Buchwald and John F. Hartwig have been credited, whose publications between 1994 and the late 2000s established …

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